8. Roberto Carlos - France v Brazil - Tournoi de France - 03/06/1997
Over 20 years later, this strike still defies physics.
Lining up a free-kick some 35+ yards from goal, the Brazilian unleashed a spectacular strike with the outside of the foot, the ball’s trajectory heading for the corner flag before seemingly impossibly bending back to leave French goalkeeper Fabien Barthez perplexed.